Abstract
Differential scanning calorimetry (DSC) measurement is used to investigate the nonisothermal crystallization behavior of poly (vinylidene fluoride) (PVDF)/polysulfone (PSF)/diethylene glycol dibenzoate (DEDB)/dibutyl phthalate (DBP) system via solid-liquid (S-L) phase separation during a thermally induced phase separation process. The effect of benzene ring in PSF on PVDF crystallization for PVDF/PSF/DEDB/DBP system is investigated. It is found that the Ozawa model can describe nonisothermal crystallization behavior of PVDF/PSF/DEDB/DBP system in a certain crystallization temperature range. Jeziorny method indicates that the secondary crystallization of PVDF exists in the process of nonisothermal crystallization and is enhanced by the increase of cooling rate.
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