Nonisothermal calorimetric study of the precipitation processes in a Cu–1Co–0.5Ti alloy

Abstract

The precipitation processes in a Cu-1.0 at.% Co-0.5 at.%Ti (Cu-1.5 at.%Co2Ti) alloy were studied using differential scanning calorimetry (DSC), transmission electron microscopy (TEM), and microhardeness measure- ments. The analysis of the calorimetric curves from room temperature to 900 K shows the presence of two exothermic reactions attributed to the formation of CoTi and Co2Ti particles in the copper matrix. On the basis of enthalpy cal- culations, it was found that the decomposition begins with the precipitation of CoTi, followed by the formation of Co2Ti particles. The activation energies calculated using the modified Kissinger method were lower than the ones corre- sponding to diffusion of cobalt and titanium in copper. Kinetic parameters were obtained by a convolution method based on the Johnson-Mehl-Avrami (JMA) formalism. The values obtained for the parameter n were indicative of a particle nucleation process from preexistent nuclei. Microhardness measurements and TEM micrographs con- firmed the formation of the mentioned phases.