Abstract
The stochastic equations of motion describing liquid-state reaction dynamics, which were developed in the previous paper, are used herein to calculate the reaction rate constant. These equations involve the consideration of both the intrinsic chemical conversion and the solvent adjustment accompanying the conversion on the same basis. Special attention is paid to the situation where the solvent adjusts very slowly, such that it is this adjustment which controls the reaction rate. For this limiting case the effective solvation coordinate becomes the reaction coordinate.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
