Abstract
A discussion about the validity of state-to-state and total weighted dissociation and recombination rate coefficients under nonequilibrium conditions is presented, both for the cases of high translational temperatures, in a shock wave, and of moderate and low temperatures, in a electrical discharge. Accurate data for these processes are obtained in N 2 using the semiclassical nonperturbative analytic method known as forced harmonic oscillator (FHO) for V– V– T and V– T energy exchanges.
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