Abstract
Ca-α-sialon compacts pressureless-sintered to intermediate temperatures, which consisted of both α-sialon and unreacted α–Si3N4 grains, were investigated with transmission electron microscopy for an overall composition Ca1.8Si6.6Al5.4O1.8N14.2. Special attention was paid to identification of the possible crystallographic orientation between a-sialon and the α–Si3N4 particles. In contrast to the frequently occurring heteroepitaxial nucleation of α-sialon in rare-earth-doped samples with low x values, this study showed that most of the newly formed α-sialon grains had no epitaxial orientation relationship with the α–Si3N4 particles, suggesting nonepitaxial heterogeneous nucleation to be a more probable mechanism for the Ca–α-sialon phase with high Ca concentrations.
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