Abstract
A new mixed-ligand nickel(II) coordination compound [Ni(bz)2(phen)2] (1) (bz = benzilate and phen = 1,10-phenanthroline) has been synthesized by refluxing nickel(II) acetate with benzilic acid and 1,10-phenantholine. Compound 1 has been characterized by elemental analysis, IR and electronic absorption spectroscopy, magnetic measurements, thermogravimetric analysis and single-crystal X-ray diffraction The crystal of 1 belongs to monoclinic crystal system, space group C2/c and its unit cell parameters are a = 25.881(3), b = 11.1728(15), c = 17.609(2) A and β = 124.104(3)°. The effect of non-covalent interactions, such as π···π and C–H···π, on the 3D supramolecular organization of this molecular complex is analyzed. A new mixed-ligand nickel(II) coordination compound [Ni(bz)2(phen)2] (1) (bz = benzilate and phen = 1,10-phenanthroline) has been synthesized and structurally characterized, the effect of non-covalent interactions, such as π···π and C–H···π, on the 3D supramolecular organization of this molecular complex has been analyzed.
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