Abstract

ABSTRACTUsing electron beam evaporation, we have deposited Al on patterned SiO2 films grown on various Si(100)-based substrates and characterized the Al films by scanning electron microscopy, x-ray diffraction and transmission electron microscopy. The growth mode of Al in the via holes of the SiO2 films is found to depend on the base materials of the holes. For via holes based on Si(100) and TiSi2, Al fills the holes nonconformally, showing little Al on the side walls. The nonconformal growth of Al is useful for submicron via-hole filling because it prevents void formation caused by shadowing effect. In contrast, for holes of AlCu bases, Al grows conformally. For the Al grown in the via holes of Si(100) bases, single crystal Al with Al(110)//Si(100) epitaxial relation can be grown in the holes at a substrate temperature of 300°C.

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