Abstract

Non-classical hydrogen bonds (NCHBs) have attracted significant interest in the past decade particularly because of their important role in asymmetric catalytic systems. These weak interactions ( 1 Introduction 2 Hydrogen Bonds (HBs) and Non-Classical Hydrogen Bonds (NCHBs) 3 Early Developments in NCHBs 4 Selected Examples of NCHBs in Organic Transformations 5 Recent Examples of NCHBs in Enantioselective Reactions 6 Conclusions and Outlook

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