Abstract
The coordination chemistry of 1-phosphafulvenes was investigated by employing their [6 + 4] adducts or α-C2-bridged biphospholes as a precursor. Unbridged phosphacymantrenes arise from 1-phosphafulvenes via proton abstraction. α-C2-bridged biphosphacymantrenes are probably yielded by the reductive coupling of 1-phosphafulvene with Mn2(CO)10. The coordination behavior of 1-phosphafulvenes is comparable to that of pentafulvenes, which again demonstrates the phosphorus-carbon analogy in low-coordinate organophosphorus chemistry.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
