Nonaqueous Electrolytes for Electrochemical Capacitors: Imidazolium Cations and Inorganic Fluorides with Organic Carbonates

Abstract

Electrolytes based on 1‐ethyl‐3‐methylimidazolium cation and either the hexafluorophosphate or tetrafluorborate anion in organic alkyl carbonate solvents have been evaluated for use in electrochemical capacitors The conductivity capacitance, limiting oxidation and reduction potentials, and thermal stability were assessed. High conductivity and capacitance values were found regardless of whether cyclic (high viscosity/high dielectric constant) or acyclic (low viscosity/low dielectric constant) alkyl carbonates were used. The best correlation with conductivity for the salt was found to be the molecular weight (κ ∝ 1/Mw) and to a lesser degree the viscosity (κ ∝ 1/η) of the solvent. The high specific capacitance (130 F/g) and excellent stability (>3.5 V, >130°C) make these electrolytes well suited for use in electrochemical double‐layer capacitors.