Abstract

The hot hydrogen atom reaction of H+CO 2→OH+CO is examined under three different experimental conditions designed to assess the effect of the initial CO 2 angular momentum distribution on the CO product energy distribution. The CO product is monitored by laser-induced fluorescence in the VUV spectral region. The CO rotational distributions in ν″=0 are reported for CO 2 reactant “temperatures” of 300, 70 and 40 K. Preliminary results on the CO ν″=1 rotational population are also presented.

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