Abstract
Thermal F atoms react with gaseous (CH 2CHCH 2) 4Ge to produce CH 2CHF through dissociation of the (CH 2CHCH 2) 3-GeCH 2CHFCH 2 * radical. The rapid decomposition is attributed to non-RRKM behavior with excitation energy largely confined to the CH 2CHFCH 2 side group. The central atoms mass effect found in linear seven-atom trajectory calculations has not yet appeared in (CH 2CHCH 2) 4M with the replacement of Sn by Ge.
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