Abstract
The non-radiative relaxation dynamics of pyrrole have been investigated using time-resolved photoelectron spectroscopy and quantum dynamics simulations. Following excitation of the A2(11πσ∗) state, we observe population flow out of the Franck-Condon region on a ≲50fs timescale. Following excitation of the B2(21ππ∗) state, we observe population being transferred to the A2(11πσ∗) state on a <50fs timescale and subsequently out of the Franck-Condon region, also on a <50fs timescale. Quantum dynamics calculations suggest that population is transferred from the B2(21ππ∗) state through the A2(1π3pz) state to the B1(21πσ∗) state before being transferred to the A2(11πσ∗) state.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
