Abstract
The pyrolytic conversion of bis-Lewis base adducts of decaborane(14), L·B10H12·L (L=neutral monophosphine) and phosphonium salts of the [B10H10]2− anion (e.g. [Ph4P+]2, etc.), to ceramic materials has been studied. All species examined served as binders for a variety of non-oxide refractory ceramic powders (e.g. B4C, BN, BP, B13P2, SiC, Si3N4, B, C, AIN).
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