Abstract

We consider a non-linear Stark effect as a model for localization and symmetry breaking of a molecule in a gas. By a comparison method with respect to the linear Stark effect, we prove the existence of level bifurcation and symmetry breaking at a critical value of the gas pressure exponentially small for large nuclear masses. Extending the Davies results, we confirm the predictions of Claverie-Jona Lasinio for pyramidal molecules as the ammonia one.

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