Abstract
A non-Gaussian treatment of the Mori theory is presented with the intention of explaining the results of recent computer simulations. The Mori equation is replaced by a multi-dimensional Markov process represented by a set of interrelated matrix equations. These are related straight-forwardly to a linear master equation and its Kramers–Moyal expansion. The non-Gaussian nature of the molecular dynamics results may then be represented by truncating the latter at third order, involving an extra operator Γ(1)L. This may be expanded in a matrix over the basis set of Hermite polynomials in terms of which may be represented eigenstates of the usual Fokker–Planck operator Γ(0)L.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
More From: Journal of the Chemical Society, Faraday Transactions 2
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.