Abstract
The phenomenological coefficients for the flows of interstitial cationsi and electronse are analyzed. Three independent phenomenological coefficientsLii,Lie, andLee are related to the diffusion coefficient of interstitial cationsDi, the transport numberti (or electric mobilityui), and the specific electric conductivityk. The fourth coefficientLi*i (describing the cross effect between cationsi* labelled in the self diffusion and unlabelled ones), connected with the effective correlation factorfeff, is related toDi,ti,ki and the tracer diffusion coefficientDi*. The generalized Nernst-Einstein relations, in which besides the electric charge also appears the electric charge of transportei*, are presented.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
