Abstract
We study the dissociation rate of N2 + N collision reaction at high temperatures from T = 10000 K to T = 40000 K. We propose a specific vibrational energy dissociation rate model based on the dynamical continuum model recently proposed by Singh et al. We calculate each vibrational energy dissociation rate of the Boltzmann and the QSS distribution. We discuss the non-Boltzmann effect that the overpopulation distribution enhances the dissociation rate. The depletion distribution reduces the dissociation rate, compared to the Boltzmann distribution.
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