Abstract

Circularly polarized luminescence (CPL) has attracted significant attention in the fields of chiral photonics and optoelectronic materials science. In a CPL-emitting system, a chiral luminophore derived from chiral molecules is usually essential, and a pair of enantiomeric luminophores is indispensable for the typical selective-emission of right- and left-handed CPL. This review focuses on non-classical CPL systems that do not use pairs of enantiomers and introduces symmetry-breaking CPL systems that do not use optically active molecules, and covers photoexcited chiral-switching, spontaneous-resolution, cryptochirality, and magnetic CPL.

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