Abstract
The electromagnetic non-bonded interactions of BN(-,0,+)B molecule as a quantum rotor inside several of BnNn molecular rings as a stator has been investigated by using EPR-II and EPR-III basis sets. Optimized structures, relative stability and hyperfine spectroscopic parameters, have been calculated.In this study, we have shown that the BnNn–BNB systems can be works as a nano rotor–stator molecular motor for the biological systems.Although in our previous works, we have discussed (Monajjemi et al. (2010) [20] and Monajjemi and Boggs (2013) [18]) of the stability and electromagnetic properties of some kind of BnNn rings, using of these systems as a detector are much more significant and have investigated in this work.The study for the BnNn–BN(-,0,+)B systems and then for Adenine–Thymine and Guanine–Cytosine base pairs coupled with BN(-,0,+)B inside the BnNn (n=8,12,15,16,18,20,24) have been investigated. Three quantized rotational frequencies in cationic, radical, and anionic forms have been calculated and all frequencies appeared in the IR rotational region.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
