Abstract

The noise-induced transition of the Zeldovich–Semenov model in a continuous stirred tank reactor is investigated under small random perturbations. The deterministic model will exhibit mono- and bistable characteristics via local and global bifurcations. In the bistable zone, based on the Freidlin–Wentzell large deviation theory, the stochastic preference is explained by analyzing the required action of the fluctuational path. For the case of monostability, in the weak noise limit, the emergence of the switching line gives rise to the sudden switch of the optimal path and the sliding cycle will appear via the sliding bifurcation, which is verified by numerical methods. In addition, when there is no saddle in phase space, stochastic excitation with large-amplitude spikes is studied. On the quasi-threshold manifold, the point with the minimum quasi-potential plays the same role as the saddle, which means that the optimal path will undergo a large excursion by crossing this special point. These phenomena are verified by employing stochastic simulations.

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