Abstract

This work presents experimental results and modeling of the combustion chemistry of the oxy-fuel (O2/CO2 recycle) combustion process with a focus on the difference in NO formation between oxy-fired and air-fired conditions. Measurements were carried out in a 100 kW test unit, designed for oxy-fuel combustion with flue gas recycling. Gas concentration and temperature profiles in the furnace were measured during combustion of lignite. The tests comprise a reference test in air and three oxy-fuel cases with different oxygen fractions in the recycled feed gas. With the burner settings used, lignite oxy-combustion with a global oxygen fraction of 25 vol % in the feed gas results in flame temperatures close to those of air-firing. Similar to previous work, the NO emission [mg/MJ] during oxy-fuel operation is reduced to less than 30% of that of air-firing. Modeling shows that this reduction is caused by increased destruction of formed and recycled NO. The reverse Zeldovich mechanism was investigated by detailed ...

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