Abstract

AbstractThe spectra of Δ3‐ and Δ4‐pyrrolin‐2‐one were analysed and the sign of all the coupling constants determined by tickling and triple resonance experiments. A positive allylic interaction (Jxz in 2) is reported and four‐bond couplings are discussed in particular. Deuterium exchange affords evidence for the tautomeric equilibrium between 1 and 2.

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