Abstract

Reaction of P 4 with Br 2 or I 2, followed by treatment of product solutions with halide substitution reagents, allowed the identification by NMR of low concentrations of exo,exoP 4Cl nBr 2-n( 1), exo,endo-P 4Cl nBr 2-n( 2, symm-P 7X 3 (X = Br or I)( 3) and P 2X nY 4-n (X = Y = two of Cl, Br, I).

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