NMR diffusion and relaxation studies during cement hydration—A non-destructive approach for clarification of the mechanism of internal post curing of cementitious materials

Abstract

Internal post-curing of hardening cement pastes by addition of alginate spheres, which contain 98% of water, is studied by non-destructive 1H NMR measurements of transverse relaxation time and self-diffusion. The onset and amount of water transition from the alginate gel used as additive with temporary delayed release of water to cement pastes was observed continuously during the dormant and accelerated period of cement hydration. During hydration, the water transition from the alginate into the cement matrix as well as the development of pore size is monitored quantitatively by studying the time dependence of characteristic peaks in the transverse relaxation time distribution. Comparison between samples without and with internal post curing shows that the addition of alginate gel does not influence the pore size in the micropore region. NMR diffusion studies demonstrate that the physically bound pore water has sufficient mobility to ensure homogeneous distribution of water from the alginate source into the surrounding cement matrix during the dormant and accelerated period.