Abstract
Structural assignment and conformational features of two diastereomeric oxidation products of 2′-deoxycytidine, the 5S* and 5R* diastereomers of N1-(2-deoxy-β-D-erythro-pentofuranosyl)-5-hydroxyhydantoin were achieved by combining NMR studies and restrained molecular dynamics. Interproton distances were measured from NOESY and ROESY experiments. The absolute configuration of these two compounds was unambiguously determined and their conformation properties in solution were also studied. © 1998 John Wiley & Sons, Ltd.
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