Abstract
AbstractThe solution structure of the InIII−bleomycin A2 complex (InBLM) has been determined by NMR studies in combination with molecular modelling. Our data indicate that BLM is coordinated to InIII through five nitrogen ligands in a distorted tetragonal pyramid configuration. The stability and homogeneity of InBLM has allowed us to obtain a well‐defined model of the complex formed at low pH, which is a very potent tumour‐imaging agent. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
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