Abstract
The nitrogen permeability and carbon dioxide solubility in poly(1-trimethylsilyl-1-propyne) (PTMSP)/poly(4-methyl-2-pentyne) (PMP) blends were studied and compared with previously reported values for PTMSP/poly( tert-butylacetylene) (PTBA) and PTMSP/poly(1-phenyl-1-propyne) (PPP) blends. The nitrogen permeability of the homopolymers follows the order: PTMSP > PMP > PTBA > PPP. This order is the same as that of their fractional free volumes, that is, the permeability of the polymers decreases with decreasing fractional free volume. The permeability of the blends obeys a simple mixing rule for homogeneous binary polymer blends. As expected, the nitrogen permeability of PTMSP/PMP blends decreases with increasing PMP content in the blend. The carbon dioxide solubility in the homopolymers follows the order: PTMSP > PMP > PTBA > PPP. This order is the same as that of the nitrogen permeability of the polymers. The carbon dioxide solubility in PTMSP/PMP blends also decreases with increasing PMP content. The sorption isotherms of PTMSP/PMP blends were analyzed based on a dual-mode sorption mechanism. The Langmuir-type solubility contributes to about 85% of the infinite dilution solubility in all PTMSP/PMP blends regardless of the PMP content. A linear correlation is observed between the nitrogen permeability and the reciprocal Langmuir capacity parameter ( C′ H ) for PTMSP-based binary blends, regardless of the blend co-component (i.e., PMP, PTBA, and PPP). Physical aging significantly reduces the nitrogen permeability of PTMSP. Relaxation of the non-equilibrium excess free volume induces a decrease in C′ H and, therefore, a decline in permeability. The permeability of the three blends showed significantly improved long-term stability compared with that of PTMSP. The permeability in all blends decreases linearly with increasing the reciprocal C′ H value. Hence, the permeability of PTMSP/substituted polyacetylene binary blends (i.e., PTMSP/PMP, PTMSP/PTBA, and PTMSP/PPP blends) can be correlated to the non-equilibrium excess free volume, regardless of the blend co-component (i.e., PMP, PTBA, and PPP).
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
