Abstract
An electron paramagnetic resonance (EPR) characterization study of isotopically enriched 12C diamond grown by General Electric has been carried out. While other commonly used techniques detect no nitrogen in this diamond, the clear EPR spectrum consistently measured a nitrogen concentration of about 0.05 ppm by calibration against a few standards. The concentration is about 2 orders of magnitude lower than that of a few natural IIa diamonds and over 4 orders of magnitude smaller than that of a typical yellow Ib diamond. The 12C diamond is evaluated to be ideal for research of diamonds under high pressure as well as irradiated diamonds. Both the experimental line shape and second moment do not support a random nitrogen distribution in this diamond. Instead, we found that nitrogen atoms tend to stay apart from one another. This uniformly dispersed nitrogen distribution is a new state of nitrogen found in diamond.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.