Nitrogen Doped Cobalt Anchored on the Used Resin-Based Catalyst to Activate Peroxymonosulfate for the Removal of Ibuprofen

Abstract

The ion exchange resin is mainly composed of carbon, and it can form carbon material after calcination in the isolation of oxygen. Meanwhile, the nitrogen doping of metal-based carbon materials has attracted extensive attention in activating peroxymonosulfate (PMS) to produce active groups in the degradation of refractory organic pollutants. In this study, the used D001 resin served as the source of carbon material and catalyst carrier, cobalt ions adsorbed by impregnation, and then mixed with dicyandiamide and carbon balls formed by calcined (N-Co/D001CB). After nitrogen doping, cobalt exists in the form of cobalt sulfide with high crystallinity, and the serious problems of skeleton shrinkage and internal blockage are significantly alleviated. Under certain catalytic reaction conditions, the degradation rate of ibuprofen in one hour was more than 95%, which was significantly higher than that of cobalt. Finally, quenching experiments found that SO4−· is the main pathway for pollutant degradation, followed by ·OH, and there also exists the contributions of ·O2− and 1O2. In summary, the catalyst was prepared easily and had efficient catalytic activity, but it also recycled its resources with a low disposal cost of used D001CB, realizing the purpose of recycling waste materials and applying them in pollutant treatment.