Abstract
The ruthenium-catalyzed direct ortho-arylation reactions of 2-phenylpyridine and 2-aryloxazolines have been successfully expanded to the direct aryl–heteroaryl coupling reactions using heteroaryl bromides. The reaction mechanism involving the Ru II/Ru IV intermediates is proposed from the results of the stoichiometric reaction of a divalent ruthenacycle complex of 2-phenylpyridine with bromobenzene.
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