Nitrogen and oxygen isotope characteristics, formation mechanism, and source apportionment of nitrate aerosols in Wuhan, Central China

Abstract

Understanding the sources and formation mechanisms of nitrate in PM2.5 is important for effective and precise prevention and control of particulate matter pollution. In this study, we detected stable nitrogen and oxygen isotope signatures of NO- 3 (expressed as δ15N-NO- 3 and δ18O-NO3−) in PM2.5 samples in Wuhan, the largest city in central China. The sources and formation pathways of NO3− were quantitatively analyzed using the modified version of the Bayesian isotope mixing (MixSIR) model, and the regional transport characteristics of NO3− were analyzed using the hybrid single-particle Lagrangian integrated trajectory (HYSPLIT) model and concentration-weighted trajectory (CWT) method. The results showed that NO3− significantly contributed to the ambient PM2.5 pollution and its driving effect increased with the gradient of pollution level. The average δ15N-NO3− and δ18O-NO3− values were 4.7 ± 0.9 ‰ and 79.7 ± 2.9 ‰, respectively. δ15N-NO3− and δ18O-NO3− were more enriched in winter and increased dramatically in heavily polluted days. The reaction pathway of NO2 + OH dominated nitrate formation in summer, while the reaction pathway of N2O5+ H2O dominated in other seasons and contributed more in polluted days than clean days. The contributions of vehicle emission, coal combustion, biomass burning, biogenic soil emission, and ship emission sources to NO3− were 26.4 %, 23.4 %, 22.8 %, 15.3 %, and 12.1 %, respectively. In addition to local emissions, air mass transport from the northern China had a significant impact on particulate NO3− in Wuhan. Overall, we should pay special attention to vehicle and ship emissions and winter coal combustion emissions in future policymaking.