Abstract
Complexes [AuCl{C(NHR)(NHR′)}] and [AuCl{C(NHR)(NEt2)}] (R = tBu, p-Tol, Xylyl, p-C6H4COOH, p-C6H4COOEt, R′ = Me, nBu, iPr, nheptyl, p-Tol) have been prepared by reaction of the corresponding isocyanogold complexes [AuCl(CNR)] with either primary amines or diethylamine. All the prepared carbenes are reactive and highly selective catalysts for skeletal rearrangement, methoxycyclization of 1,6-enynes, and other mechanistically related gold-catalyzed transformations. Overall, these easily accessible nitrogen acyclic carbene (NAC) gold complexes were not second to NHC complexes and were advantageous to obtain different products.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have