Year-end Sale % OFF 
Abstract
Numerous ionic compounds containing the guanidinium ion have been investigated by means of nitrogen-14 nuclear quadrupole resonance techniques. The nitrogen resonance spectrum of the amino groups of the quanidinium ions yielded, with a few exceptions, an average e 2qQ/h = 3553.6 kHz and an average asymmetry parameter η = 0.39493. The Townes-Dailey theory is employed in interpreting the quadrupole coupling data to yield the electronic populations of the bonds. In two cases (guanidinium acetate and guanidinium carbonate) large deviations from the average quadrupole coupling parameters were observed. These deviations are interpreted, by means of a modified Townes-Dailey theory, to indicate that hydrogen bonds are formed between the guanidinium ions and the anions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
