Abstract
The crystal structure of oxido-nitro-gen(1+) tetra-fluorido-borate (nitro-sonium tetra-fluorido-borate), NO+BF4 -, was refined on the basis of single-crystal X-ray diffraction data at 150 K. The compound crystallizes in the baryte structure type with ortho-rhom-bic Pnma symmetry. The crystal structure exhibits cationic disorder with equal occupation of N and O atoms at the same site.
Highlights
The crystal structure of oxidonitrogen(1+) tetrafluoridoborate, NO+BF4À, was refined on the basis of single-crystal X-ray diffraction data at 150 K
For nitrosonium tetrafluoridoborate (NOBF4), which is an efficient oneelectron oxidant, nitrosating and diazotizing agent (Olah et al, 2004), only the unit-cell parameters derived from X-ray powder diffraction data have been reported previously (a = 6.983 A, b = 8.911 A, c = 5.675 A, space group Pbnm; Evans et al, 1964)
Nitrosonium tetrafluoridoborate crystallizes in the baryte (BaSO4) structure type and is isotypic with ammonium, alkali metal (K, Rb, Cs) (Clark & Lynton, 1969) and dioxygen(1+) tetrafluoridoborates (Wilson et al, 1971)
Summary
The crystal structure of oxidonitrogen(1+) tetrafluoridoborate (nitrosonium tetrafluoridoborate), NO+BF4À, was refined on the basis of single-crystal X-ray diffraction data at 150 K. The compound crystallizes in the baryte structure type with orthorhombic Pnma symmetry. The crystal structure exhibits cationic disorder with equal occupation of N and O atoms at the same site
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