Abstract

AbstractThe scope of polyformal formation from nitro‐ and fluorodiols has been explored further with a series of α, ω‐diols. Polymers with M̄ns of 2000–4000 were generally obtained but M̄ns approaching 10,000 are possible in some cases. Effects of monomer structure and reaction parameters on polymer molecular weight are described. The polymers were characterized by GPC, 1H‐NMR, and DSC analysis.

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