Abstract
The mol-ecular structure of the title compound, [Ag(NO2)(C21H21P)2], exhibits a pseudo-tetra-hedral coordination around the central AgI atom. The compound crystallizes with one mol-ecule in the asymmetric unit in the monoclinic space group P21/n with a rather long b axis [33.8752 (2) Å]. Weak C-H⋯O and C-H⋯N inter-actions consolidate the crystal packing. The nitrite-O atoms each occupy a single position in the coordination geometry.
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