Abstract
1. Nitration of methylenediamine derivatives RN(X)CH2N(X)R by nitronium tetrafluoroborate was accompanied by cleavage of the N-X (X=MeCO) or N-CH2 (X=RSO2, RO2C bond and formation of N-nitro derivatives of methylenediamine or N-nitro amides, respectively. 2. During nitration of methylenediamine derivatives RSO2N(X)CH2R2 by nitronium tetrafluoroborate, the amine nitrogen (X=H) or both nitrogen atoms (X=Me) underwent attack. 3. The direction of the nitration reaction depended on the nature of the nitrating agent (NO2BF4 and HNO3).
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