Abstract

Abstract9‐Nitrocarbazole (1) was prepared and rearranged to give a mixture of 1‐nitro‐ (2) and 3‐nitrocarbazole (3) in the same ratio as observed in the case of the carbazole nitration. The evidence for the formation of 1 during the nitration of carbazole in acetic acid is given. The formation of C‐nitro compounds during methylation of the 1,3,6,8‐tetrachlorocarbazole/1,3,6,8‐tetrachloro‐9‐nitrocarbazole complex can be explained by an alkali‐catalysed nitramine rearrangement. The mechanism of this rearrangement is discussed.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.