Nitrate transport in the chalk vadose zone in Picardy, France

Abstract

Abstract Since the 1980s, nitrate has been shown to be present in soils and the vadose zone of various types of geological materials years after fertilizer application. In chalk, where the vadose zone is thick, nitrate storage can be considerable and its transport time towards groundwater can be lengthy. In this context, evaluation of the impact of changes in agricultural practices on groundwater quality remains a major question. Improvement of groundwater quality can in certain cases be greatly delayed after the implementation of environmental agricultural practices. The principal objective of this study is to improve our knowledge of when changes in agricultural practices will have a noticeable effect on groundwater quality. To meet this objective, nitrate concentration profiles were performed in agricultural plots in Picardy (France). A crop marker event was used to calculate the transport velocity of water and associated solutes. This method is useful when other tracers (such as tritium or chloride) cannot be used. Estimated velocities range from 0.51 to 0.54 m a −1 ; these values are similar to those described in similar chalk aquifers.