Abstract
AbstractA single‐chain magnet (SCM) with 1D EO‐azide‐cobalt chains has been previously synthesized from a solvothermal reaction of Co(NO3)2, NaN3, and 1,4‐bis(imidazol‐1‐yl)benzene (bib). Herein the template HNO3 is introduced into the above reaction system and another new coordination polymer (1) is obtained, which exhibits an α‐Po framework with 1D EE‐azide‐cobalt chains. The magnetic property of 1 has been well studied, and the results show spin‐canted antiferromagnetism and slow relaxation of magnetization.
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