NiSe2 encapsulated in N-doped TiN/carbon nanoparticles intertwined with CNTs for enhanced Na-ion storage by pseudocapacitance

Abstract

Transitional metal selenides are considered as potential anode candidates for sodium-ion batteries (SIBs) because of their relatively high theoretical capacity and environmental benign. However, the large volume change derived from the conversion reaction and the sluggish kinetics due to the inherent low electrochemical conductivity hinder their practical application. Herein, composite materials of NiSe2 encapsulated in nitrogen-doped TiN/carbon nanoparticles with carbon nanotubes (CNTs) on the surface (NiSe2@N-TCP/CNTs) are fabricated via pyrolysis and selenization processes. In this composite, TiN inside the carbon matrix can enhance the conductivity and structural stability. CNTs that are in-situ grown on the surface not only further enhance the conductivity of the composites, but also offer sufficient space to buffer the volume expansion and alleviate serious aggregation of NiSe2 nanoparticles. Benefit from these merits, the NiSe2@N-TCP/CNTs showed a lower charge transfer resistance and a faster Na+ diffusion rate than materials without growing CNTs. When used as the anode of SIBs, the NiSe2@N-TCP/CNTs electrode delivered a reversible capacity of 344.0 mAh g−1 after 1000 cycles at 0.2 A g−1, and still maintained at 272.7 mAh g−1 even at a high current density of 2 A g−1. The remarkable electrochemical performance is mainly attributed to the special designed hierarchical structures and pseudocapacitance sodium storage behavior.