NiO Decorated Ti/TiO2 Nanotube Arrays (TiO2NT)/TiO2/g-C3N4 Step-Scheme Heterostructure Thin Film Photocatalyst with Enhanced Photocatalytic Activity for Water Splitting

Abstract

A new strategy to enhance the photocatalytic properties of graphitic carbon nitride is reported via constructing an effective NiO decorated Ti/TiO2NT/TiO2/g-C3N4 S-scheme heterostructure photocatalyst thin film (Ti/TiO2NT/TiO2/g-C3N4/NiO). This thin film photocatalyst can separate hydrogen gas and oxygen gas into different sides of the Ti substrate. Owing to the synergistic effect of the NiO as co-catalyst and the formation of Step-scheme (S-scheme) heterojunction between g-C3N4 and TiO2, the electrons and holes were successfully separated to their opposing active centers, which is beneficial to inhibiting the recombination of the charge carriers. The gas evolution rate of Ti/TiO2NT/TiO2/g-C3N4/NiO is 7.97 μmol h−1 cm−2 under the irradiation of high-pressure mercury lamp, which was 3 and 1.3 times as high as that of the Ti/TiO2NT/g-C3N4 and Ti/TiO2NT/TiO2/g-C3N4, respectively. Firstly, benefiting from the well-matched band structure, a direct S-scheme Ti/TiO2NT/g-C3N4 heterojunction thin film is constructed easily driven by the built-in electric field across the Ti/TiO2NT/g-C3N4 interface. Furthermore, the introduction of the TiO2 layer on the TiO2NT will broaden light absorption range and increase the heterojunction area, which in turn conduces to effective charge separation. In addition, NiO as a co-catalyst cannot only accelerate the charge separation but also provide plentiful catalytic sites and decompose H2O2 produced by g-C3N4. The thin film photocatalysts can be recycled again, which is different from traditional powdered photocatalysts. This work constructs a NiO decorated Ti/TiO2NT/TiO2/g-C3N4 S-scheme heterostructure photocatalyst thin film, and provides a new insight to promote photocatalytic activity of g-C3N4 under the synergetic impact of S-scheme heterostructure and NiO co-catalyst. A novel NiO decorated Ti/TiO2NT/TiO2/g-C3N4 S-scheme heterostructure photocatalyst thin film was fabricated to enhance photocatalytic activity for water splitting.