Abstract

The maximum-entropy distribution functions applied to Callaway's model for phonon gas dynamics lead to a hierarchy of closed systems of moment equations. The system of equations for the energy density and the heat flux is the first member of this hierarchy of closures. Here emphasis is placed on analysing the next member, the 9-moment maximum-entropy system that involves the flux of the heat flux as an extra gas-state variable. After presenting a study of the one-dimensional, rotationally symmetric reduction of this system, we explicitly calculate a single generating function of three Lagrange multipliers in terms of which the reduced system of three evolution equations for these multipliers can be cast into a symmetric hyperbolic form. In the context of determining the Lagrange multipliers as explicit functions of the moment densities, we discuss new aspects of the expansion of various non-equilibrium quantities about quasi-equilibrium states. This expansion is fundamentally a non-equilibrium expansion that includes the heat flux in a non-perturbative manner, i.e., there are no unphysical limitations on the magnitude of the nonvanishing component of the heat flux to maintain a theory. Results are presented both at the first order in the expansion and at the second order. This enables us to verify the internal consistency of our approach and to justify the non-equilibrium generalization of the method of Grad.

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