Nighttime residential wood burning evidenced from an indirect method for estimating real-time concentration of particulate organic matter (POM)

Abstract

Real-time analyzers of selected chemical components (sulfate, nitrate, Black Carbon) and integrative aerosol parameters (particulate matter and light scattering coefficient) were implemented for a 2-week campaign (November–December 2005) in a suburban area of Clermont-Ferrand (France) in order to document fast changes in the chemical composition of submicron aerosols. Measurements of particulate organic matter (POM) were not available in the field but were indirectly estimated from time-resolved (3-min) reconstruction of the light scattering coefficient. This methodology offered the opportunity to investigate almost real-time and artifact-free POM concentrations even at low concentrations (typically below 0.1 μg m −3). The overall uncertainties associated with this POM calculation were of the order of 20%, which are comparable to those commonly referred in literature for POM calculation or measurements. A chemical mass balance (CMB) of PM 1 was performed using the derived POM concentrations and showed a very good correlation (slope=0.93; r 2=0.91, N=663) with real-time PM 1 measurements obtained from R&P TEOM-FDMS, demonstrating the consistency of our approach. Important diurnal variations were observed in POM concentrations, with a dominant contribution of POM from fossil fuel origin during daytime and a dominant contribution of POM from residential wood burning at night. POM was calculated to contribute as much as 70% of PM 1 during our study, pointing out the major role of carbonaceous aerosols at this period of the year at our residential area.