Ni–Fe mixed oxides prepared by calcination of layered double hydroxides: Potential pigments for the ceramic industry

Abstract

Mixed Ni,Fe oxides have been prepared by calcination of precursors with the hydrotalcite-type structure which had been prepared by the reverse micelle method using different surfactants. The solids have been characterized by several physicochemical techniques: Powder X-ray diffraction, nitrogen adsorption–desorption at −196°C for specific surface area assessment, particle size distribution, UV–vis spectroscopy, and temperature-programmed reduction. The solids are formed by NiO and NiFe2O4 (spinel) and their properties depend on the experimental conditions used to prepare the hydrotalcite-type precursor. The crystallite size is larger for the spinel crystallites than for the NiO crystallites and in all cases depends on the surfactant used and the pH during the synthesis. The original, uncalcined samples, show intense mainly yellow color, but on calcination almost all of them change to dark brown or even almost black; only when using a cyclic surfactant the color is markedly different from that obtained when linear surfactants are used.