Abstract
A rigid nicotinate-modified lanthanide-substituted selenotungstate [H2N(CH3)2]6Na3H[La4SeW8(H2O)16(nica)2O28][SeW9O33]2·32H2O (1, Hnica = nicotinic acid) was synthesized and consists of two trivacant Keggin [B-α-SeW9O33]8- fragments and one unusual [SeW4O18]8- fragment bridged by a heterometallic [La4W4(H2O)16(nica)2O28]18- cluster. In the heterometallic cluster, two carboxyl O atoms in two nicotinate ligands directly coordinate with two W atoms in a stable C-O-W-O-W-O six-membered ring fashion. According to its catalase-like activity, 1 was utilized to catalyze the oxidation of 3,3',5,5'-tetramethylbenzidine (TMB) by H2O2 to produce blue oxidized TMB (ox-TMB), which can be used to establish a colorimetric sensing method for the detection of ascorbic acid. This work not only provides a promising platform for detecting H2O2 and ascorbic acid but also expands the application potential of polyoxometalate-based materials in biological and clinical analyses.
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