Nickel Sulfide/Hierarchical Porous Carbon from Spent Residue Hydrocracking Catalyst as Electrocatalyst for the Oxygen Evolution Reaction.

Abstract

Spent residue slurry-phase hydrocracking catalyst coated with coke have been classified as hazardous solid waste, presenting serious economic and environmental issues to refiners. Herein, the spent catalysts with a nickel sulfide nanoparticle/coke hierarchical structure (NiSX /C) from our previous work were used to prepare nickel sulfide/hierarchical porous carbon (NiSX /HPC) for the oxygen evolution reaction (OER) through the method of carbonization, activation, and sulfurization. The results indicate that the NiSX /C converts into Ni/HPC after carbonization and activation, and then transform into NiSX /HPC by sulfurization. The optimized NiSX /HPC-8 possesses the crystal phase of NiS2 , and the high specific surface area of 1134.9 m2 g-1 with the hierarchical micro-mesoporous structure. Besides, NiSX /HPC-8 achieves a low overpotential of 236 mV at 10 mA cm-2 , a low Tafel slope of 64.1 mV dec-1 , and excellent stability. This work provides a viable method for upcycling spent catalysts to re-constructed OER catalysts with high catalytic performance and durability.