Abstract

Nanocomposite sensors were prepared using carbon soot (CNPs), nickel oxide nanoparticles (NiO-NPs), and cellulose acetate (CA), which was used to detect and study the sensing mechanism of mesitylene vapour at room temperature. Synthesised materials were characterised using high-resolution transmission electron microscopy (HR-TEM), powder x-ray diffraction (PXRD), Raman spectroscopy, and nitrogen sorption at 77 K. Various sensors were prepared using individual nanomaterials (NiO-NPs, CNPs, and CA), binary combinations of the nanomaterials (CNPs-NiO, CNPs-CA, and NiO-CA), and ternary composites (NiO-CNPs-CA). Among all of the prepared and tested sensors, the ternary nanocomposites (NiO-CNPs-CA) were found to be the most sensitive for the detection of mesitylene, with acceptable response recovery times. Fourier-transform infrared (FTIR) spectroscopy coupled with an LCR meter revealed that the mesitylene decomposes into carbon dioxide.

Highlights

  • IntroductionThe detection of mesitylene vapour is very important due to the fact that the inhalation of this vapour can result in various health concerns

  • There is a high demand for environmental monitoring sensing devices for volatile organic compounds (VOCs), such as methane [1], methanol [2], ethanol [3], triethylamine [4], acetone [5], toluene [6], xylene, ethylbenzene [7], and the under-reported toxic mesitylene.The detection of mesitylene vapour is very important due to the fact that the inhalation of this vapour can result in various health concerns

  • It was found that the Nickel oxide (NiO) were mainly cubic particles but with some spherical and hexagonal structures, and the cubic shapes observed correlates well with NiO nanoparticles powder

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Summary

Introduction

The detection of mesitylene vapour is very important due to the fact that the inhalation of this vapour can result in various health concerns. Mesitylene is an organic compound, known as 1,3,5-trimethylbenzene, with a vapour pressure of about 2.49 mmHg at room temperature. It is commonly found in mixed liquids of detergents, inks, and some paints. People working in an open or closed environment that involves painting cars or petroleum companies, as examples, are likely to be affected. People who worked in the painting industries were noted to have anemia and bronchitis as the paints contain about

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