Abstract
AbstractReported is a highly enantioselective Ni(0)‐catalyzed endo‐selective C−H annulation of 2‐ and 4‐pyridone, and 4‐pyrimidone with alkenes to provide drug‐relevant bicyclic heterocycle products. The use of a readily prepared chiral bulky NHC ligand (SIPE) for Ni catalyst and commercially available AlEt3 as co‐catalyst enhanced the practicality of this reaction.magnified image
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